Crystal Structure of KTi[sub 0.93]Sn[sub 0.07]OPO[sub 4].

Autor: Wen, Liu, Sorokina, N. I., Voronkova, V. I., Yanovskiı, V. K., Verin, I. A., Vigdorchik, A. G., Simonov, V. I.
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Zdroj: Crystallography Reports; May2000, Vol. 45 Issue 3, p386, 3p
Abstrakt: To reveal correlations between the atomic structure and properties of the KTi[sub 1-x]Sn[sub x]OPO[sub 4] solid solutions, single crystals of the KTi[sub 0.93]Sn[sub 0.07]OPO[sub 4] composition were synthesized and their structure was determined. The crystals belong to the KTiOPO[sub 4] family; orthorhombic, sp. gr. Pna2[sub 1]. The unit-cell parameters are a = 12.831, b = 6.410, and c = 10.584 Å. The partial substitution of Sn atoms for Ti atoms results in the formation of more symmetric coordination polyhedra in the structure framework and the change of the physical properties of the crystals. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index