Anomalous Behavior of the Fluorescence Spectra of Perylene in n-Octane under Pressure and Temperature Variations.

Autor: Balashov, S. N., Karpov, V. P., Korotaev, O. N., Shchanov, M. F.
Předmět:
Zdroj: Journal of Experimental & Theoretical Physics; Nov2001, Vol. 93 Issue 5, p998, 6p
Abstrakt: Pressure-induced transformations of the vibronic spectra of perylene in n-octane were studied. An increase in pressure from normal to 10 kbar caused a sharp change in the multiplet structure of the spectra. An anomalous, almost linear temperature dependence of spectral line widths was observed in the temperature range 4.2-15 K. Both temperature and baric effects were explained in terms of the same model of a two-well adiabatic potential of impurity centers, which caused the appearance of low-frequency splittings in the ground and excited electronic level regions. [ABSTRACT FROM AUTHOR]
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