Electronic absorption spectra of protonated 2-(2-furyl)pyrroles, 2-(2-thienyl)pyrroles, and 2-arylpyrroles.

Autor: Strashnikova, N., Sigalov, M., Korostova, S., Mikhaleva, A., Trofimov, B.
Zdroj: Russian Chemical Bulletin; 1993, Vol. 42 Issue 6, p1013-1015, 3p
Abstrakt: Protonation of 2-(2-furyl)-, 2-(2-thienyl)-, and 2-arylpyrroles by sulfuric acid in ethanol was studied using electronic absorption Spectroscopy in the UV and visible regions. Pyrroles with heteroaromatic substituents are protonated at the α-positions of pyrrole and the heterocycle, resulting in the appearance of additional long-wave spectral bands. In the series of 2-arylpyrroles protonation capability is determined by the electronic effect of the phenyl ring substituents. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index