Transformed steroids.

Autor: Turuta, A., Dzhlantiashvili, N., Voishvillo, N.
Zdroj: Russian Chemical Bulletin; 1993, Vol. 42 Issue 5, p946-949, 4p
Abstrakt: The approaches to the synthesis of various 16α,17α-disubstituted pregna-4,9-dien-3,20-diones from the corresponding 9α-derivatives with labile epoxide, dioxolane, and oxathiolane rings D′ have been studied. The transformation has been found to proceed efficiently when the 9α-sulfinic esters are used at the intermediate stage and then elimination of sulfinic acid by TsOH/SiO is carried out. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index