Autor: |
Mamedov, V., Valeeva, V., Antokhina, L., Nuretdinov, I. |
Zdroj: |
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1991, Vol. 40 Issue 6, p1262-1266, 5p |
Abstrakt: |
The reaction of methyl 3-phenyl-3-chloro-2-oxopropionate with thiosemicarbazones proceeds via the intermediate formation of methyl [S-(1′-alkylideneisothiosemicarbazidyl)]-3-phenyl-2-oxopropionate hydrochlorides, which then cyclize to novel 4-methoxycarbonyl-5-phenyl-2-substituted thiazoles. Hydrolysis of the intermediate products and the thiazoles obtained therefrom with simultaneous distillation of the carbonyl compound affords 2-hydrazino-4-methoxy-carbonyl-5-phenylthiazole. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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