Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes.

Autor: Ushakov, N., Bakulina, G., Patrikeev, A., Portnykh, E., Oppengeim, V., Finkel'shtein, E.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1991, Vol. 40 Issue 4, p838-841, 4p
Abstrakt: The Diels-Alder reactions of 1,2-dimethylenecyclobutane with vinyltrichlorosilane and vinylmethyldichlorosilane give the corresponding trichlorosilyl and methyldichlorosilyl derivatives of cyclobutene. Methylation of these derivatives gave 4-trimethylsilylbicyclo[4.2.0]oct-1-ene, which underwent thermal isomerization to 4-trimethylsilyl-1,2-dimethylcyclohexane. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index