Mechanism of oxidation of cyclohexane by the radical cation of pyridine N-Oxide.

Autor: Kulakovskaya, S., Shamaev, S., Berdnikov, V.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1990, Vol. 39 Issue 7, p1345-1348, 4p
Abstrakt: Oxidation of pyridine N-oxide in the presence of cyclohexane was studied on platinum and carbon glass rotating disk electrodes using the method of cyclic voltammetry in 0.2 N LiClO in acetonitrile. It was hypothesized that the electrochemically generated N-oxide radical cation reacts with cyclohexane according to the mechanism of hydrogen atom cleavage. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index