| Autor: |
Dzhemilev, U., Gaisin, R., Turchin, A., Khalikova, N., Baikova, I., Tolstikov, G. |
| Zdroj: |
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1990, Vol. 39 Issue 5, p967-974, 8p |
| Abstrakt: |
We have investigated the reductive dehalogenation reaction of alkyl and aryl substituted gem-dihalocyclopropanes with diisobutyl aluminum hydride in the presence of catalytic amounts of titanium and zirconium complexes. As a result we propose a general method for the synthesis of substituted monohalocyclopropanes and cyclopropanes of various structures. We have also studied the stereochemistry of the reduction. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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