Interaction of vicinal N-methyl and C-isopropyl substituents in 3-ketopiperidines: Ring configuration and stereochemistry of carbonyl reactions.

Autor: Katvalyan, G., Mistryukov, E., Shashkov, A.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1990, Vol. 39 Issue 4, p776-781, 6p
Abstrakt: The cis- and trans-1,5-dimethyl-2-isopropyl-3-piperidones were synthesized. Their configurations were determined usingH andC NMR spectroscopy. The stereochemistry of the hydride and catalytic reduction of the resulting 3-piperidones was studied. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index