| Autor: |
Meskina, M., Baider, L., Skibida, I. |
| Zdroj: |
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1990, Vol. 39 Issue 4, p646-650, 5p |
| Abstrakt: |
Kinetic investigation of the reaction of electrochemically generated $$0_2 ^{\mathop - \limits_ \bullet } $$ with perfluorooctene, styrene, and cyclohexene in acetonitrile, in the presence of tetraethylammonium perchlorate used as a background electrolyte, revealed that $$0_2 ^{\mathop - \limits_ \bullet } $$ reacts with styrene and perfluorooctene at the double bond, and the reactivity of the olefins with respect to $$0_2 ^{\mathop - \limits_ \bullet } $$ decreases with decrease in the electrophilicity of the substituents at the double bond: perfluorooctene > styrene > cyclohexene. The main transformation products of styrene are phthalic and benzoic acid esters. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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