Dual reactivity of diphenylphosphinous and phenylphosphonous acid amides in reactions with N-acetoxymethyl-substituted diethylamine, benzamide, and acetamide.

Autor: Ivanov, B., Krokhina, S., Chichkanova, T., Ageeva, A.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1986, Vol. 35 Issue 12, p2535-2539, 5p
Abstrakt: N-Acetoxymethyldiethylamine reacts with tetraethyldiamidophenylphosphonite and diethylamidodiphenylphosphinite, and N-acetoxymethylbenzamide with tetraethyldiamidophenylphosphonite at the phosphorus atom only to form Arbuzov reaction products. The reaction of N-acetoxymethylacetamide with tetraethyldiamidophenylphosphonite and diethylamidodiphenylphosphinite, and the reaction of N-acetoxymethylbenzamide with diethylamidodiphenylphosphinite proceed at two reaction centers at the phosphorus atom to form the Arbuzov reaction products, and at the nitrogen atom to form acetoxyphosphinites (phosphonites) and N-diethylaminomethylamides. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index