Condensation of perfluoroisobutylene with perfluorinated vinyl alkyl ethers.

Autor: Postovoi, S., Zeifman, Yu., Knunyants, I.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1986, Vol. 35 Issue 6, p1186-1189, 4p
Abstrakt: Condensation of perfluoroisobutylene with perfluorovinyl alkyl ethers with CsF catalysis takes place according to a scheme of concerted nueleophilic addition, with participation of the perfluoro-tert-butyl anion as nucleophile and perfluoroisobutylene as electrophile. In the presence of CO the product of concerted perfluoroalkylcarboxylation forms. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index