Spectroscopic study of germanium-containing compounds.

Autor: Chipanina, N., Sarapulova, G., Bravo-Zhivotovskii, D., Pigarev, S., Byazankina, O., Frolov, Yu., Vyazankin, N.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1984, Vol. 33 Issue 2, p310-313, 4p
Abstrakt: The values of γC=0 in the IR spectra and the position of the band from the n → π electronic transition in the UV spectra of the amides RCONRR vary linearly with the inductive effect of the R substituent (for R=R=H, Alk). This may indicate the absence of the intramolecular coordination Ge ← 0, where or. The substituent R=Ge(CH) exhibits electron-acceptor properties besides a +I-effect. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index