| Autor: |
Voronkov, M., Roman, V., Maletina, E., Korotaeva, I. |
| Zdroj: |
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1982, Vol. 31 Issue 3, p621-623, 3p |
| Abstrakt: |
The reaction of bis(trimethylsilyl) sulfate (BTS) with HBr leads to trimethylbromosilane, hexamethyldisiloxane, and free bromine. Its reaction products with HI are hexamethyldisiloxane and free iodine. The reaction of BTS with PCl leads to the formation of MeSiCl, SO, and a polymeric product whose composition approximates [(CH)SiO]ClOPS. The reaction of SOCl with BTS gives in high yield MeSiOSOCl, MeSiCl, and SO. POCl and SOCl do not react with BTS under analogous conditions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
