Carbonylation of aliphatic and cyclic alcohols by carbon monoxide in the presence of complexes of BF with acetic, propionic, or monochloroacetic acid.

Autor: Pirozhkov, S., Puzitskii, K., Myshenkova, T., Ryabova, K., Éidus, Ya.
Zdroj: Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1977, Vol. 26 Issue 4, p744-750, 7p
Abstrakt: The complexes BF-2CHCHCOOH and BF·2CHCOOH and the system 3BF·2CHClCOOH-BF·2CH-COOH are active and stable catalysts of the carbonylation reaction (80-100°, p=100 atm) of tertiary and secondary alcohols of aliphatic and cyclic structure with formation of carboxylic acids in high yields and can be used repeatedly without a decrease in the initial activity. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index