Autor: |
Aldoshin, S., Utenyshev, A., Metelitsa, A., Knyazhanskii, M., Lyashik, O., Medyantseva, E., Minkin, V. |
Zdroj: |
Russian Chemical Bulletin; 1996, Vol. 45 Issue 9, p2184-2188, 5p |
Abstrakt: |
New fulgides of the indole series with adamantylidene fragments were synthesized: 3-(adamant-2-ylidene)-2-[1′-(3′-indolylethylidene)]succinic anhydride ( I) and 3-(adamant-2-ylidene)-2-(3′-indolylmethylene)]succinic anhydride ( 2). By means of electronic absorption andH NMR spectroscopy and X-ray diffraction analysis, fulgides 1 and 2 were shown to have Z- and E-configurations, respectively. The photochemical properties of 1 and 2 were studied. It was shown that along with Z-E photoisomerization of these compounds, in solution they undergo a cyclization reaction to yield a colored photoproduct. Specific structural features of fulgide 1 affecting its photochemical properties were discussed. The introduction of a bulky adamantylidene group decreases the extent of the conversion of compound 1 into cyclic isomer C. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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