Structures of bis(cyclopentadienyl) binuclear titanium complexes.

Autor: Mkoyan, Sh., Aliev, Z., Urazovskii, I., Atovmyan, L., Nifant'ev, I., Butakov, K.
Zdroj: Russian Chemical Bulletin; 1996, Vol. 45 Issue 9, p2154-2156, 3p
Abstrakt: The (CH-XMe-CH) · (TiCl) binuclear complexes, where X = Si ( 1) or C ( 2), have been studied by X-ray structural analysis. In both structures, the coordination polyhedra about the Ti atoms are distorted tetrahedra formed by three CI atoms and one Cp ring. The conformations of molecules 1 and 2 and the possibility of the occurrence of secondary Ti-Cp...Cl-Ti interaction are discussed [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index