Exo-H- and endo-H-η-pentamethylcyclopentadiene complexes of platinum.

Autor: Gusev, O., Morozova, L., Peganova, T., Petrovskii, P., Ustynyuk, N.
Zdroj: Russian Chemical Bulletin; 1994, Vol. 43 Issue 3, p474-477, 4p
Abstrakt: A mixture of endo-H and exo-H isomers ( 1a and 1b) of the (η-CMeH)PtCl complex was prepared by the reaction of KPtCl with CMeH in MeOH. The mixture of isomers reacts with CpTl in the presence of TiBF to give a novel complex, [(η-CMeH)Pt(η-CH)]BF, as a mixture of endo-H- and exo-H-isomers ( 2a and 2b). The data ofH andC NMR spectroscopy of the resulting complexes are discussed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index