Autor: |
Gewald, Karl, Hain, Ute |
Zdroj: |
Chemical Monthly / Monatshefte für Chemie; 1992, Vol. 123 Issue 5, p455-459, 5p |
Abstrakt: |
β-Chloro-α-cyano-cinnamonitrile (1) reacts in one step with α-oxo-thioles 3 or successively with sodium sulphide and α-chlorocarbonyl compounds 4 to form the 5-substituted 4-amino-2-phenyl-thiophene-3-carbonitriles 5. Analogously, the successive reactions of β-chloro cinnamonitrile 1 with sodium selenide - produced in situ from selene and sodium boronhydride - and α-chlorocarbonyl compounds 4 yields the 5-substituted 4-amino-2-phenyl-selenophene-3-carbonitriles 6. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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