JOF, seine Struktur und F-Ionen-Akzeptor-Eigenschaften.

Autor: Engelbrecht, A., Mayr, O., Ziller, G., Schandara, E.
Zdroj: Chemical Monthly / Monatshefte für Chemie; 1974, Vol. 105 Issue 4, p796-806, 11p
Abstrakt: IOF, originally assumed to have a trigonal bipyramidal structure, is polymeric. Mass spectra confirm the existence of molecules with molecular weights up to three times the formula weight. Chemically, IOF is a strong Lewis acid and fluorine ion acceptor, thus forming the anion IOF. With SbF it forms a further polymeric compound (IOF·SbF).F-NMR, mass, IR and Raman spectra confirm the proposed structures. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index