Breakthrough in the α-Perchlorination of Acyl Chlorides.

Autor: Bellesia, Franco, D'Anna, Francesca, Felluga, Fulvia, Frenna, Vincenzo, Ghelfi, Franco, Parsons, Andrew F., Reverberi, Federico, Spinelli, Domenico
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Zdroj: Synthesis; 2012, Vol. 2012 Issue 7, p605-609, 5p
Abstrakt: The preparation of α-perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index