The first synthesis of a transition metal-catalyzed homopolymer having pendent t-boc-protected quinizarin for patterned fluorescence images.

Autor: Yoo, Jimmy, Lee, Jae-Hyoung, Cho, Iwhan, Ahn, Kwang-Duk, Kim, Jong-Man
Zdroj: Macromolecular Research; Jan2003, Vol. 11 Issue 1, p69-72, 4p
Abstrakt: A homopolymer having pendent t-Boc-protected quinizarin moieties has been prepared for patterned fluorescence images. The homopolymer P{ t-BQN (2-norbornenylmethyl di- tert-butoxycarbonylquinizarin)} 5 was prepared by palladium-catalyzed addition polymerization. The t-Boc-protecting groups of the polymer were efficiently removed during chemical amplification process and revealed original properties of quinizarin, allowing patterned fluorescence images in the polymer film. [ABSTRACT FROM AUTHOR]
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