Synthesis, structure and electrochemical behaviour of cobalt(II) complexes with 2,6- bis(benzimidazol-2′-yl) pyridine.

Autor: Wang, Shuangxi, Yu, Shuyan, Luo, Qinhui, Wang, Qiuying, Shi, Jianqui, Wu, Qiangjin
Zdroj: Transition Metal Chemistry; Apr1994, Vol. 19 Issue 2, p205-208, 4p
Abstrakt: The complexes Co(BBP)Cl, Co(BBP)SO·HO, Co(BBP)(NO)·HO, Co(BBP)(ClO) and Co(BBP−H)· 2HO, where BBP is 2,6- bis(benzimidazol-2′-yl) pyridine, were prepared and characterized by elemental analysis, electrical conductance, i.r. and electronic spectra. The electrochemical behaviour of the complexes was recorded and the X-ray crystal structure of Co(BBP)Cl(MeOH) was determined. The geometry about cobalt is a distorted octahedron. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index