| Autor: |
Markó, László, Palágyi, József |
| Zdroj: |
Transition Metal Chemistry; Aug1983, Vol. 8 Issue 4, p207-209, 3p |
| Abstrakt: |
The hydrogenation of aldehydes and ketones with molecular hydrogen is catalyzed by Fe(CO) as catalyst precursor if a tertiary amine is used as solvent. The actual catalyst system is probably HFe(CO) and the protonated amine. The amine also functions as a base and therefore more strongly basic amines like EtN yield more active catalysts. Oxygen bases (even strong ones) furnish rather inefficient catalyst systems. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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