Influence of temperature on quenching of fluorescence in compounds of the coumarin series.

Autor: Sakhno, T., Korotkova, I., Khakhel, O.
Zdroj: Theoretical & Experimental Chemistry; Jul1996, Vol. 32 Issue 4, p217-220, 4p
Abstrakt: A study has been made of the influence of temperature on the quantum yield of fluorescence of 3,4-benzocoumarin in ethanol or n-hexane, in the temperature interval 77-300 K. A mechanism of fluorescence quenching is proposed, consisting of thermal 'activation' of intercombination conversion between neighboring energy levels that differ in orbital nature. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index