Molecular and ionic forms of salts and H-complexes in solutions.

Autor: Gol'dshtein, I., Perepelkova, T., Petrov, É.
Zdroj: Theoretical & Experimental Chemistry; Sep1995, Vol. 31 Issue 5, p217-229, 13p
Abstrakt: We generalize data collected in recent years on the effect of the properties of the medium on the state of salts and H-complexes in solutions. We examine current ideas about the molecular structure of these compounds in low-polarity media and the role of solvation effects in stabilization of ionic forms. We show the interconnection between changes in the electronic structure of the salts and H complexes occurring under the influence of the solvent and the thermodynamics of respectively ionic dissociation and proton transfer. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index