Electronic structure of active centers and kinetic stereocontrol in polymerization of butadiene under the influence of a catalytic system based on neodymium chloride.

Autor: Sabirov, Z., Mintshenkova, N., Kazantseva, I., Urazbaev, V., Monakov, Yu.
Zdroj: Theoretical & Experimental Chemistry; Nov1991, Vol. 27 Issue 6, p643-646, 4p
Abstrakt: On the basis of quantum-chemical calculations of models of active centers, a suggested mechanism of kinetic stereocontrol of the microsctructure in polymerization of butadiene under the influence of the catalytic system NdCl · 3TBP-HA1 (i-CH) has been verified experimentally. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index