Electronic structure and thermodynamic properties of dimeric mixed-valence clusters.

Autor: Belinskii, M., Tsukerblat, B., Botsan, I., Belinskaya, I.
Zdroj: Theoretical & Experimental Chemistry; Mar1987, Vol. 23 Issue 2, p141-149, 9p
Abstrakt: A many-electron theory is proposed for exchange and tunneling levels of dimeric mixed-valence clusters. Transition-metal ions are examined, and it is established that the parameters of the Heisenberg and double-exchange interactions depend on the configuration of the d-electronic states. Temperature dependences are constructed for the effective magnetic moments and the electronic heat capacity. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index