Calorimetric absorption spectroscopy of J-aggregate dye monolayers below 0.1 Kelvin.

Autor: Gruhl, H., Dorn, H., Winzer, K.
Zdroj: Applied Physics B: Lasers & Optics; Nov1985, Vol. 38 Issue 3, p199-203, 5p
Abstrakt: We describe an extremely sensitive method to investigate nonradiative processes following optical excitation. In a low-temperature calorimeter, the sample is irradiated with monochromatic light. The absorbed energy which is converted into phonons leads to a measurable increase of the sample temperature. The lowest detectable dissipated energy is 2·10J at a working temperature of 0.03 K. We demonstrate our method with a calorimetric absorption spectrum of J-aggregate monolayers of 1-methyl-1′-octadecyl-2,2′-cyanine. From this spectrum the emission quantum efficiency is obtained as a function of excitation wavelength. A relative minimum is found at the long wavelength edge of the absorption band at 582.5 nm. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index