Study of reaction and kinetics in pyrolysis of methyl ricinoleate.

Autor: Guobin, Han, Zuyu, Liu, Suling, Yao, Rufeng, Yan
Zdroj: Journal of the American Oil Chemists' Society (JAOCS); Sep1996, Vol. 73 Issue 9, p1109-1112, 4p
Abstrakt: The effects of pyrolysis temperature, space-velocity, and dilution ratio of starting materials on the reaction have been studied in the pyrolysis of methyl ricinoleate. The reaction parameters were optimized to obtain yield ranges of 25.8-26.7% for heptaldehyde and 45.7-46.5% for methyl undecenoate. The kinetic study showed that pyrolysis of methyl ricinoleate is a first-order reaction at 828-878 K, and the activation energy is 1.729×10 j/mol. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index