Novel bis (crown ether)-based potassium sensor for biological applications.

Autor: Lindner, Ernö, Tóth, Klára, Jeney, Judit, Horváth, Mária, Pungor, Ernö, Bitter, István, Ágai, Béla, Töke, László
Zdroj: Microchimica Acta; 1990, Vol. 100 Issue 3/4, p157-168, 12p
Abstrakt: Based on structure-selectivity studies on bis-benzo-crown ether derivatives, 2,2′-bis[3,4-(15-crown-5)-2-nitrophenylcarbamoxymethyl]tetradecane (BME-44) was designed and synthesized. The performance characteristics of this new, highly lipophilic ionophore of the group of bis-nitrobenzo-15-crown-5 derivatives with urethane linkage when used in liquid membrane electrodes are evaluated with special regard to the requirements of biological and clinical applications. Potentiometric steady-state and flow-through dynamic data are presented to prove the sensor capabilities for clinical and physiological potassium determinations. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index