The effects of temperature and humidity on phenol-formaldehyde resin bonding.

Autor: Wang, Xiang-Ming, Riedl, Bernard, Christiansen, Alfred, Geimer, Robert
Zdroj: Wood Science & Technology; Jun1995, Vol. 29 Issue 4, p253-266, 14p
Abstrakt: The effects of temperature and relative humidity on phenol-formaldehyde resin bonding were evaluated. Two flakes in a lap-shear configuration were bonded under an environment of controlled temperature (110 °C, 120 °C, 130 °C, 140 °C) and relative humidity (41%, 75%, 90%) for a series of time periods (0.25 to 16 min). The lap-shear specimens were then shear-tested on a mechanical testing machine and the results were used to establish a family of bond strength development curves at each temperature and level of relative humidity. At 110°C, the higher relative humidity appeared to retard resin bonding. The effects of relative humidity diminished as temperature increased to 140 °C. Bond strength development was chemical ratecontrolled. The rate of bond strength development at each relative humidity follows a first order reaction mechanism. The activation energy of resin-wood bonding, determined by bonding kinetics, was higher than that of resin alone, determined by differential scanning calorimetry. This comparison indicates that to form a strong resin-wood bond, a higher energy level might be required. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index