Cationic telomerization of isobutylene.

Autor: Clouet, F., Zwick, V., Franta, E., Brossas, J.
Zdroj: Polymer Bulletin; 1982, Vol. 7 Issue 9/10, p449-455, 7p
Abstrakt: Cationic telomerization has been attempted by reacting BF onto isobutylene in the presence of acetic anhydride: Under proper experimental conditions, we obtained only one product - a cetoester monoadduct CHCOCH-C(CH)-O-COCH -. In order to study the initiation step, we have reacted a preformed salt CHCOSbF onto isobutylene in the presence of acetic anhydride and shown that the acetylium salt is efficient and that termination by esterification is surprisingly high. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index