| Autor: |
Klein, Jakob, Klesper, Ernst |
| Zdroj: |
Polymer Bulletin; 1982, Vol. 6 Issue 5/6, p291-298, 8p |
| Abstrakt: |
Syndiotactic poly(methallyl alcohol) was esterified with selected carboxylic acids under complete conversion to the corresponding homopolymers. Reactions were carried out in HBr-acetic acid to yield acetate; with pivaloyl chloride or phthalic anhydride to obtain pivalate and acid phthalate, respectively, as well as with the N-protected amino acids, N-phthaloyl-glycine, N-phthaloyl-L-phenylalanine or N-carbobenzoxy-L-tryptophane in the presence of dicyclohexylcarbodiimide (DCC) or 1-ethoxycarbonyl-2-ethoxy-1.2-dihydroquinoline (EEDQ) to yield N-protected amino acid ester side chains. Conversion and structure of the polymers were confirmed by H- and C-NMR spectra. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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