Efficient preparation of trans-α,β-unsaturated aldehydes from saturated aldehydes by oxidative enamine catalysis.

Autor:	Zhang, ShiLei, Xie, HeXin, Song, AiGuo, Wu, DeYan, Zhu, Jin, Zhao, SiHan, Li, Jian, Yu, XinHong, Wang, Wei
Zdroj:	SCIENCE CHINA Chemistry; Dec2011, Vol. 54 Issue 12, p1932-1936, 5p
Abstrakt:	A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to ( E) selective α,β-unsaturated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink