Decay processes of the C[sub 2] [sup 2]Π[sub 1/2u] states of Ar[sub 2][sup +], Kr[sub 2][sup +], and Xe[sub 2][sup +].

Autor: Yoshii, H., Hayaishi, T., Onuma, T., Aoto, T., Morioka, Y., Ito, K.
Předmět:
Zdroj: Journal of Chemical Physics; 7/22/2002, Vol. 117 Issue 4, p1517, 5p, 7 Graphs
Abstrakt: The threshold photoelectron photoion coincidence spectra of the rare gas dimers Ar[sub 2], Kr[sub 2], and Xe[sub 2] have been measured in the photon energy region between the first and second dissociation limits of the dimer ions. It has been found that the C[sub 2] ²Π[sub 1/2u] states of Kr[sup +][sub 2] and Xe[sup +][sub 2] completely dissociate via an optical transition to the repulsive B[sub 2] ²Π[sub 1/2g] state, while that of Ar[sup +][sub 2] does not dissociate. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index