Polarization effects of a europium complex in stretched polyethylene.

Autor: Srdanov, V. I., Robinson, M. R., Bartl, M. H., Bu, X., Bazan, G. C.
Předmět:
Zdroj: Applied Physics Letters; 4/29/2002, Vol. 80 Issue 17, p3042, 3p, 2 Charts, 2 Graphs
Abstrakt: Polarization effects in photoluminescence spectra of Eu[sup 3+] ions in tris(dinaphthoylmethane) (monophenanthroline)europium(III) complex [abbreviated hereafter as Eu(dnm)[sub 3]phen] dispersed in stretched polyethylene (PE) reveal quasi-uniaxial alignment of the molecular complex, not present in the unstretched PE. The ligand field structure of Eu[sup 3+] [sup 5]D[sub 0]–[sup 7]F[sub 2] transition in the Eu(dnm)[sub 3]phen single crystal differs from that of a single molecule in stretched PE, indicating rearrangement of the organic ligands upon stretching. © 2002 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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