Self-assembly of highly crystalline two-dimensional MOF sheets on liquid surfacesElectronic supplementary information (ESI) available: The experimental supplementary information contains details of the film preparation and measurement conditions, π–aisotherms, IR and UV-vis spectra and the azimuthal dependence of GIXRD profiles. See DOI: 10.1039/c1ce05684k

Autor: Rie Makiura, Kohei Tsuchiyama, Osami Sakata
Předmět:
Zdroj: CrystEngComm; Aug2011, Vol. 13 Issue 18, p5538-5541, 4p
Abstrakt: The formation process of the highly crystalline MOF nanosheet, NAFS-1 at the liquid surface was studied by UV-visible spectroscopy and synchrotron grazing incidence X-ray diffraction – self-assembly of the molecular building metalloporphyrin units and the metal ion joints occurs through a coordination reaction at the air/liquid interface without the necessity of pressing the surface. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index