Two tetrahydrofuran solvates of HN(SePPh2)2.

Autor: Pernin, Christopher G., Ibers, James A.
Zdroj: Acta Crystallographica: Section C (Wiley-Blackwell); Mar2000, Vol. 56 Issue 3, p376-378, 3p
Abstrakt: The X-ray crystal structures of P, P′-imino­bis­(di­phenyl­seleno­phosphine) tetra­hydro­furan solvate, C24H21NP2Se2·C4H8O, (I), and bis­(tetra­hydro­furan) solvate, C24H21NP2Se2·2C4H8O, (II), have been determined; (I) has twofold crystallographic symmetry. In each compound, the O atom of one mol­ecule of tetra­hydro­furan is hydrogen bonded to the amide-H atom of HN(SePPh2)2. The conformation of the Se-P-N-P-Se chains in (I), (II), and the crystal structure of the unsolvated HN(SePPh2)2 are different. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index