Thermovoltaic properties of hornet silk.

Autor: Volynchik, S., Plotkin, M., Ermakov, N.Y., Bergman, D.J., Ishay, J.S.
Zdroj: Microscopy Research & Technique; Nov2006, Vol. 69 Issue 11, p852-860, 9p
Abstrakt: In silk from the larval silk caps of the Oriental hornet Vespa orientalis (Hymenoptera, Vespinae), temperature-dependent changes in the electric voltage have been recorded, with rise in the voltage occurring mainly upon rise in the temperature between 10-36°C. The peak voltage was measured between 32-38°C and attained 240-360 mV, but with further increase in temperature, the voltage decreased, dropping to 0 mV at about 45-50°C. Upon second measurement (of same silk specimen), the voltage peak usually occurred later (by 8-9°C) and at higher temperature than in the first measurement. Continuous measurements during warming up to 30°C followed by cooling down to 15°C yielded an hysteresis between the warming 'line' and the cooling 'line', the former often straight and the latter usually curved. Maintaining the silk specimen at a fixed temperature for a prolonged period (hours) initially causes the voltage to rise, then remain steady, and finally drop. Boiling the silk caps in tap water for 7-10 min exerts some changes in the silk properties, mainly a decrease in voltage level. The general behavior of the silk suggests that it is a polymer endowed with the qualities of an organic semiconductor. The various properties of the larval silk are discussed in great detail. Microsc. Res. Tech., 2006. © 2006 Wiley-Liss, Inc. [ABSTRACT FROM AUTHOR]
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