| Autor: |
Akasaka, T., Wakahara, T., Nagase, S., Kobayashi, K., Waelchli, M., Yamamoto, K., Kondo, M., Shirakura, S., Maeda, Y., Kato, T., Kato, M., Nakadaira, Y., Gao, X., Caemelbecke, E. Van, Kadish, K. M. |
| Předmět: |
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| Zdroj: |
AIP Conference Proceedings; 2001, Vol. 590 Issue 1, p465, 4p |
| Abstrakt: |
The anion of La...C[sub 82] was electrochemically prepared and isolated. Anionic La...C[sub 82](-) is very stable in water, even after exposure to air at room temperature. The high stability of La...C[sub 82](-) is essentially due to its closed-shell electronic structure. As evidenced by the ESR analysis, La...C[sub 82](-) is diamagnetic. These experimental timings are confirmed by density functional calculations. The cage structure of La...C[sub 82] was determined for the first time and shown to have C[sub 2v] symmetry based on the [sup 13]C NMR measurements of the compound in its anionic form. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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