| Autor: |
Han, Q., Cheng, Y., Li, J., Wang, J. |
| Předmět: |
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| Zdroj: |
Russian Journal of Coordination Chemistry; Jul2011, Vol. 37 Issue 7, p547-551, 5p |
| Abstrakt: |
new Keggin-type heteropolyanion decorated with dinuclear copper-organic coordination ions, {[Cu(Phen)(μ-Cl)Cu(Phen)][SiWO]}· HO ( I), has been hydrothermally synthesized and structurally characterized by IR spectroscopy and single-crystal X-ray diffraction. X-ray crystallography analysis showed that two dinuclear copper-organic [Cu(Phen)(μ-Cl)Cu(Phen)] units are supported on the reduced α-Keggin polyoxoanion [SiWO] via two terminal oxygen atoms from opposite sides of the Keggin polyoxoanion, and I further acts as a neutral molecular unit for the construction of a one-dimensional chain-like framework by $C - H \cdots Cl$ hydrogen bonds and π-π-stacking interactions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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