Rotationally resolved quenching and relaxation of CH(A[sup 2]Δ,v=0,N) in the presence of CO.

Autor: Meden, P., Kind, M., Stuhl, F.
Předmět:
Zdroj: Journal of Chemical Physics; 2/15/2002, Vol. 116 Issue 7, p2757, 6p, 3 Charts, 5 Graphs
Abstrakt: Kinetic properties of the single rotational states 2≤N≤8 of the electronically excited CH(A[sup 2]Δ,v=0) radical have been studied in the gas phase at room temperature in the presence of CO. Rate constants of the state-to-state relaxation are presented. Further, rate constants were determined for the electronic quenching of single N states and compared with data recently reported by Cerezo and Martin [J. Photochem. Photobiol., A 134, 127 (2000)]. The radiative lifetimes of the rotational levels are given, too. © 2002 American Institute of Physics. [ABSTRACT FROM AUTHOR]
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