| Autor: |
Lapidus, A., Eliseev, O., Zvyagintsev, N., Kondrat'ev, L. |
| Zdroj: |
Russian Journal of Physical Chemistry; May2011, Vol. 85 Issue 5, p786-789, 4p |
| Abstrakt: |
The influence of a catalyst on regioselectivity of styrene carbonylation in ionic liquids catalyzed by palladium(II) complexes was studied. The mechanism of the migration insertion of styrene at the palladium-hydrogen bond determining the regioselectrivity of the whole reaction, which is treated as electrophilic addition to the multiple bond of styrene, was studied. A study of the structure of intermediate complexes formed at this stage was performed using the B3LYP method of density functional theory. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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