| Autor: |
Muhammad Arif Nadeem, Aaron W. Thornton, Matthew R. Hill, John Arron Stride |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; Mar2011, Vol. 40 Issue 13, p3398-3401, 4p |
| Abstrakt: |
A microporous metal–organic framework [Cu3(ipO)2(pyz)2]n, (ipO = 2-hydroxyisophthalic acid, pyz = pyrazine) was synthesized viaan in situ.ligand transformation reaction. The microporous framework displays helical arrays of ipo ligands holding the Cu atoms in 2D sheets, whilst the coordination of pyz molecules acts to arrange these sheets into a microporous 3D structure. Remarkable selective sorption behaviour (>5) for H2over N2is observed and explained with molecular dynamics simulations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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