Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+AlCl4−and comparison with imidazolium based systems.

Autor: Abood, Hadi M. A., Abbott, Andrew P., Ballantyne, Andrew D., Ryder, Karl S.
Předmět:
Zdroj: Chemical Communications; Mar2011, Vol. 47 Issue 12, p3523-3525, 3p
Abstrakt: The addition of a simple amide to AlCl3causes the formation of a liquid of the form [AlCl2·nAmide]+AlCl4−. The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index