| Autor: |
Denny, R. Aldrin, Reichman, David R. |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 2/1/2002, Vol. 116 Issue 5, p1987, 8p, 5 Graphs |
| Abstrakt: |
Building upon the framework of the preceding paper, a molecular hydrodynamic theory of the fifth-order (two-dimensional) nonresonant Raman spectrum in a simple liquid is presented. A multi-time mode-coupling-like theory is developed and compared with recent computer simulations for liquid Xe. The theory is able to provide a microscopic rationale for the absence of an echo in this system. Experimental predictions for the temperature and density dependence of the signal are presented. Comparison is made with the instantaneous-normal-mode theory. The limitations of the present approach are discussed.© 2002 American Institute of Physics. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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