| Autor: |
Vasireddy, Sivakumar, Ganguly, Sreemoyee, Sauer, Joe, Cook, Wyndham, Spivey, James J |
| Předmět: |
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| Zdroj: |
Chemical Communications; Dec2010, Vol. 47 Issue 2, p785-787, 3p |
| Abstrakt: |
The direct gas phase catalytic oligomerization of methane at temperatures ≤673 K has been demonstrated using AlBr3-HBr superacid. The reaction produces C2+ hydrocarbons and hydrogen in a single step at 1 atm in a continuous flow reactor at a nominal residence time of 60 s. The essentially complete conversion of methane appears to be due to protolytic activation of methane in the presence of H+AlBr4−. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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