Spontaneous resolution of a new diphosphonate-functionalized polyoxomolybdateElectronic supplementary information (ESI) available: Complementary figures for the crystal structures, IR, UV, TG spectra, XRD of compound 1. CCDC reference numbers 749910(1a) and 749908(1b). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0ce00104j

Autor: Hua-Qiao Tan, Wei-Lin Chen, Ding Liu, Yang-Guang Li, En-Bo Wang
Předmět:
Zdroj: CrystEngComm; Dec2010, Vol. 12 Issue 12, p4017-4019, 3p
Abstrakt: A new diphosphonate-functionalized polyoxomolybdate l,d-(NH4)6{MoV2O4[(MoVI2O6)NH3CH2CH2CH2C(O)(PO3)2]2}·10H2O (1) has been synthesized by the reaction of alendronic acid with {Mo2O4(H2O)6}2+fragments. In the structure, a restriction of “folding” alkyl induced chiral polyoxometalate has been observed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index