1-[(Pyridine-2-ylamino)methyl]pyrrolidine-2,5-dione: Supramolecular Aggregation via Cooperative H-bonded Network of N-H···N and C-H···O Interactions.

Autor:	Tamilvendan, Dhanapal, Prabhu, Ganesan, Fronczek, Frank, Vembu, Nagarajan
Předmět:	CLUSTERING of particles MOLECULAR structure HYDROGEN bonding PYRROLIDINE SUCCINIMIDES DIMERS CHEMICAL processes
Zdroj:	Journal of Chemical Crystallography; Nov2010, Vol. 40 Issue 11, p981-984, 4p
Abstrakt:	In the crystal structure of the title compound, CHNO, the pyrrolidine ring adopts a puckered envelope conformation. The supramolecular architecture is dictated by the cooperative H-bonded network of centrosymmetric dimers of N-H···N and C-H···O interactions. Two edge to face C-H···π interactions involving the centroid of the pyrrolidine ring contribute to the supramolecular aggregation. Graphical Abstract: The supramolecular architecture of 1-[(pyridine-2-ylamino)methyl]pyrrolidine-2,5-dione is dictated by the cooperative H-bonded network of centrosymmetric dimers of N-H···N and C-H···O interactions. Two edge to face C-H···π interactions involving the centroid of the pyrrolidine ring contribute to the supramolecular aggregation.[Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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